dc.contributor.advisor | Chval, Zdeněk | |
dc.contributor.author | Dvořáčková, Olga | |
dc.date.accessioned | 2025-03-06T08:06:36Z | |
dc.date.available | 2025-03-06T08:06:36Z | |
dc.date.issued | 2022 | |
dc.date.submitted | 2022-02-17 | |
dc.identifier.uri | https://dspace.jcu.cz/handle/20.500.14390/46277 | |
dc.description.abstract | Complexes of platinum and other transition metals are important compounds with many applications including anticancer treatment. This thesis is based on the computational studies dealing with the properties and reactivity of square planar complexes. We showed that the central metal atom acts as a Lewis acid in standard coordination bonds but is able to interact as a Lewis base when being in contact with a Lewis acid. Substitution(s) of the nonleaving ligand(s) enabled a fine-tuning of the reactivity of Pt(II) compounds. | cze |
dc.format | 92 s. | |
dc.format | 92 s. | |
dc.language.iso | cze | |
dc.publisher | Jihočeská univerzita | cze |
dc.rights | Bez omezení | |
dc.subject | platinum | eng |
dc.subject | Lewis acid | eng |
dc.subject | Lewis base | eng |
dc.subject | reactivity | eng |
dc.subject | substitution effect | eng |
dc.subject | trans effect | eng |
dc.title | Acid/base properties and reactivity of square planar complexes | cze |
dc.title.alternative | Acid/base properties and reactivity of square planar complexes | eng |
dc.type | disertační práce | cze |
dc.identifier.stag | 67476 | |
dc.description.abstract-translated | Complexes of platinum and other transition metals are important compounds with many applications including anticancer treatment. This thesis is based on the computational studies dealing with the properties and reactivity of square planar complexes. We showed that the central metal atom acts as a Lewis acid in standard coordination bonds but is able to interact as a Lewis base when being in contact with a Lewis acid. Substitution(s) of the nonleaving ligand(s) enabled a fine-tuning of the reactivity of Pt(II) compounds. | eng |
dc.date.accepted | 2022-04-27 | |
dc.description.department | Přírodovědecká fakulta | cze |
dc.thesis.degree-discipline | Biofyzika | cze |
dc.thesis.degree-grantor | Jihočeská univerzita. Přírodovědecká fakulta | cze |
dc.thesis.degree-name | Ph.D. | |
dc.thesis.degree-program | Biofyzika | cze |
dc.description.grade | Dokončená práce s úspěšnou obhajobou | cze |
dc.contributor.referee | Carrasco, José Pedro Cerón | |
dc.contributor.referee | Rulíšek, Lubomír | |
dc.contributor.referee | Srnec, Martin | |